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SharePoint 2010- Cant add Users to groups

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Okay on my SharePoint server, when i want to grant a user permission to lets say the Owner's group, i go and search for the user in A.D find Him, and when i add him i get this error,

Server error in '/'Application. the same happens when i say select a user to view his permissions in SharePoint, i get the same service, also in IIS i had a look at the accounts that the application pools are using and they are a domain account with the correct rights to connect to A.D.

In event log this is the event.

Event code: 3005 Event message: An unhandled exception has occurred. Event time: 10/11/2012 10:02:47 AM Event time (UTC): 10/11/2012 8:02:47 AM Event ID: d902e2fa97c9449aa7b5cc4ed017723b Event sequence: 2913 Event occurrence: 5 Event detail code: 0

Application information: Application domain: /LM/W3SVC/1901200390/ROOT-1-129944117181445077 Trust level: WSS_Minimal Application Virtual Path: / Application Path: C:\inetpub\wwwroot\wss\VirtualDirectories\80\ Machine name:

Process information: Process ID: 1000 Process name: w3wp.exe Account name: Domain\user

Exception information: Exception type: InvalidOperationException Exception message: There is an error in XML document (1, 43).

Request information: Request URL: http://www.website.ac.za/_layouts/aclinv.aspx?IsDlg=1 Request path: /_layouts/aclinv.aspx User host address:
User: 0#.w|Domain\User Is authenticated: True Authentication Type: Federation Thread account name: Domain\User

Thread information: Thread ID: 26 Thread account name: Domain\User Is impersonating: False Stack trace: at System.Xml.Serialization.XmlSerializer.Deserialize(XmlReader xmlReader, String encodingStyle, XmlDeserializationEvents events) at System.Xml.Serialization.XmlSerializer.Deserialize(XmlReader xmlReader) at Microsoft.SharePoint.WebControls.EntityEditor.ParseSpanData(String spans) at Microsoft.SharePoint.WebControls.EntityEditor.LoadPostData(String postDataKey, NameValueCollection values) at System.Web.UI.Page.ProcessPostData(NameValueCollection postData, Boolean fBeforeLoad) at System.Web.UI.Page.ProcessRequestMain(Boolean includeStagesBeforeAsyncPoint, Boolean includeStagesAfterAsyncPoint)

Custom event details:

Does somebody maybe have a solution for me on this?


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