Looked at the server log and I am getting a ID 6398
The Execute method of job definition Microsoft.Office.Server.UserProfiles.LMTRepopulationJob (ID d3c12453-3047-4534-b791-84658d5666de) threw an exception. More information is included below.
Unexpected exception in FeedCacheService.IsRepopulationNeeded: Unable to create a DataCache. SPDistributedCache is probably down..
I have a 4 tier farm.
DB, Search, WFE, APP
I had Distributed Cache only installed on WFE and tried starting UPSS but was getting this error. So I added the Distributed Cache service back onto APP and started it. Still same error.